Atkins Physical Chemistry(Seventh Edition)（物理化学）（第7版） 下载 pdf 百度网盘 epub 免费 2025 电子版 mobi 在线

由Peter Atkins等教授编著的Phvsical Chemistry是国外优秀的物理化学教材之一，被国内一些高等学校用作物理化学课程的教学参考书。随着近年来“双语”教学工作的开展，部分高等学校相继在物理化学课程的“双语”教学中使用了该教材，深受读者欢迎。

该教材自初版以来，作者不断地对其进行补充和修订，平均每四年再版一次，本书是第七版(2002年出版)。

全书分为平衡篇、结构篇和速率篇共二十九章。每一章前均有本章内容框架提示；每一章后均列出了本章的重要概念和公式以及参考阅读资料的目录，并配有本章的练习题和思考题。全书后附有物理化学常用数据表、习题答案和索引。

本书第七版更加注重与科学研究前沿的衔接，在新增设的37个专栏中提供了大量的与生物、材料、环境、工程和天体等研究领域相关的应用实例，以便学生更深入地理解物理化学的内涵和外延。在页边注释和补充资料中列出了更多的数学推导，并在因特网上提供了可自我设定参数的在线图表，以帮助学生更全面地掌握课程内容。

本书可作为高等院校化学、化工及有关专业的教学用书，也可供有关科研和工程技术人员参考使用。

Part 1 Equilibrium

　1 The properties of gases

　2 The First Law: the concepts

　3 The First Law: the machinery

　4 The Second Law: the concepts

　5 The Second Law: the machinery

　6 Physicaltransformations of pure substances

　7 Simple mixtures

　8 Phase diagrams

　9 Chemical equilibrium

　10 Equilibrium electrochemistry

Part 2 Structure

　11 Quantum theory: introduction and principles

　12 Quantum theory: techniques and applications

　13 Atomic structure and atomic spectra

　14 Molecular structure

　15 Molecular symmetry

　16 Spectroscopy 1: rotational and vibrational spectra

　17 Spectroscopy 2: electronic transitions

　18 Spectroscopy 3: magnetic resonance

　19 Statistical thermodynamics: the concepts

　20 Statistical thermodynamics: the machinery

　21 Molecular interactions

　22 Macromolecules and aggregates

　23 The solid state

Part 3 Change

　24 Molecules in motion

　25 The rates of chemical reactions

　26 The kinetics of complex reactions

　27 Molecular reaction dynamics

　28 Processes at solid surfaces

　29 Dynamics of electron transfer

Further information 1: Mathematical techniques

Further information 2: Essential concepts of physics

Data section

Answers to exercises

Answers to problems

Index

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A reversible change in thermodynamics is a change that can be reversed by an infinitesimal modification of a variable. The key word 'infinitesimal' sharpens the everyday meaning of the word 'reversible' as something that can change direction. We say that a system is in equilibrium with its surroundings if an infinitesimal change in the conditions in opposite directions results in opposite changes in its state.

Intermolecular forces are so important when the temperature is so low that the molecules travel with such low mean speed that can be captrued by one another.

At low pressures, when the sample occupies a large volume, the molecular are so far apart for most of the time that the intermolecular forces plya no significant role, and the gas behaves virtually perfectly.

At moderate pressures, when the average separation of the moleculer is only a few molecular diameters, the attractive forces dominate the repulsive forces. In this case, the gas can be expected to be more compressible than a perfect gas because the forces help to draw the molecules together.

At high pressures, when the average separation of the molecules is small, the repulsive force dominate and the gas can be expected to be les...

At very low pressures, all the gases shown have ≈ 1 and behave nearly perfectly.

At high pressures, all the gases have Z > 1, signifying that they have a larger volume than a perfect. Repulsive forcess are now dominant.

At intermediave pressures, most gases have Z < 1, indicating that the attractive forces are reducing the molar volume relative to that of a perfect gas.

书籍介绍

Atkins物理化学（第7版影印版国外优秀化学教学用书），ISBN：9787040193428，作者：（英）阿特金斯、（美）葆拉